Publications

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42) Obisesan, S.V.; Rose, C.; Farnum, B.H.; Goldsmith, C.R.* “Co(II) Complex with a Covalently Attached Pendent Quinol Selectively Reduces O₂ to H₂O” J. Am. Chem. Soc. 2022, 144, 22826-22830.

41) Mazumder, M.M.R.; Dalpati, N.; Pokkuluri, P.R.; Farnum, B.H.* “Zinc-Catalyzed Two-Electron Nickel(IV/II) Redox Couple for Multi-Electron Storage in Redox Flow Batteries” Inorg. Chem. 2022, 61, 19039-19048. Featured Article

40) Chown, A.L.; Yeasmin, H.; Paudel, R.; Comes, R.B.; Farnum, B.H.* “Lithium Dependent Electrochemistry of p-Type Nanocrystalline CuCrO₂ Films” ChemElectroChem 2022, 9, e202200825. Special Issue: Electrochemical Solar Energy Conversion and Storage (Selected for Cover Feature)

39) Chown, A.L.; Farnum, B.H.* “Defining the Role of Cr³⁺ as a Reductant in the Hydrothermal Synthesis of CuCrO₂ Delafossite” Inorg. Chem. 2022, 61, 8349-8355.

38) Bredar, A.R.C.^a; Blanchet, M.D.^a; Burton, A.R.; Matthews, B.E.; Spurgeon, S.R.; Comes, R.B.*; Farnum, B.H.* “Oxygen Reduction Electrocatalysis with Epitaxially Grown Spinel MnFe₂O₄ and Fe₃O₄“ ACS Catal. 2022, 12, 3577-3588. (^aEqual Contribution)

37) Burton, A.R.^a; Paudel, R.^a; Matthews, B.E.; Sassi, M.; Spurgeon, S.R.; Farnum, B.H.*; Comes, R.B.* “Thickness Dependent OER Electrocatalysis of Epitaxial LaFeO₃ Thin Films” J. Mater. Chem. A 2022, 10, 1909-1918. (^aEqual Contribution)

36) Mazumder, M.M.R.; Burton, A.R.; Richburg, C.S.; Saha, S.; Cronin, B.; Duin, E.C.; Farnum, B.H.* “Controlling One-Electron vs Two-Electron Pathways in the Multi-Electron Redox Cycle of Nickel Diethyldithiocarbamate” Inorg. Chem. 2021, 60, 13388-13399.

35) Gibson, N.^a; Bredar, A.R.C.^a; Chakraborty, N.; Farnum, B. H.* “Group 13 Lewis Acid Catalyzed Synthesis of Metal Oxide Nanocrystals via Hydroxide Transmetallation” Nanoscale 2021, 13, 11505-11517. (^aEqual Contribution)

34) Saha, S.; Sahil, S.T.; Mazumder, M.M.R.; Stephens, A.M.; Cronin, B.; Duin, E.C.: Jurss, J.W.; Farnum, B.H.* “Synthesis, Characterization, and Electrocatalytic Activity of Bis(pyridylimino)isoindoline Cu(II) and Ni(II) Complexes” Dalton Trans. 2021, 50, 926-935.

33) Bredar, A.R.C.^a; Chown, A.L.^a; Burton, A.R.^a; Farnum, B.H.* “Electrochemical Impedance Spectroscopy of Metal Oxide Electrodes for Energy Applications” ACS Appl. Energy Mater. 2020, 3, 66-98. (^aEqual Contribution) Special Issue: Young Investigator Forum

32) Zhen, M.; Huang, Z.; Ji, H; Qiu, F.; Zhao, D.*; Bredar, A.R.C., Farnum, B.H. “Simultaneous Control of Soil Erosion and Arsenic Leaching at Disturbed Land using Polyacrylamide Modified Magnetite Nanoparticles” Sci. Total Environ. 2020, 702, 134997.

31) Kokal, R.K.; Bredar, A.R.C.; Farnum, B.H.; Deepa, M.* “Solid State Succinonitrile/Sulfide Hole Transport Layer and Carbon Fabric Counter Electrode for a Quantum Dot Solar Cell” ACS Appl. Nano Mater. 2019, 2, 7880-7887.

30) Richburg, C.S.; Farnum, B.H.* “Influence of Pyridine on the Multielectron Redox Cycle of Nickel Diethyldithiocarbamate” Inorg. Chem. 2019, 58, 15371-15384.

29) Bredar, A.R.C.; Blanchet, M.D.; Comes, R.B.; Farnum, B.H.* “Evidence and Influence of Copper Vacancies in p-Type CuGaO₂ Mesoporous Films” ACS Appl. Energy Mater. 2019, 2, 19-28. Special Issue: New Strategies to Advance the Quest for Solar Fuels

28) Niklas, J.E.; Farnum, B.H.; Gorden, J.D.; Gorden, A.E.V.* “Structural Characterization and Redox Activity of a Uranyl Dimer and Transition Metal Complexes of a Tetradentate BIAN Ligand” Organometallics 2017, 36, 4626-4634.

Prior to Auburn University

27) Wang, D.; Farnum, B.H.; Dares, C.J.; Meyer, T.J.* “Chemical Approaches to Artificial Photosynthesis: A Molecular, Dye-Sensitized Photoanode for O2 Production Prepared by Layer-by-Layer Self-Assembly” J. Chem. Phys. 2020, 152, 244706.

26) Wang, D.; Sampaio, R.N.; Troian-Gautier, L.; Marquard, S.L.; Farnum, B.H.; Sherman, B.D.; Sheridan, M.V.; Dares, C.J.; Meyer, G.J.; Meyer, T.J.* “Molecular Photoelectrode for Water Oxidation Inspired by Photosystem II” J. Am. Chem. Soc. 2019, 141, 7926-7933.

25) Wang, D.; Wang, Y.; Brady, M.D.; Sheridan, M.V.; Sherman, B.D.; Farnum, B.H.; Liu, Y.; Marquard, S.L.; Meyer, G.J.; Dares, C.J.; Meyer, T.J.* “A Donor-Chromophore-Catalyst Assembly for Solar CO₂ Reduction” Chem. Sci. 2019, 10, 4436-4444.

24) Wang, D.; Marquard, S.L.; Troian-Gautier, L.; Sheridan, M.V.; Sherman, B.D.; Wang, Y.; Eberhart, M.S.; Farnum, B.H.; Dares, C.J.*; Meyer, T.J.* “Interfacial Deposition of Ru(II) Bipyridine-Dicarboxylate Complexes by Ligand Substitution for Applications in Water Oxidation Catalysis” J. Am. Chem. Soc. 2018, 140, 719-726.

23) Wang, D.; Sherman, B.D.; Farnum, B.H.; Sheridan, M.V.; Marquard, S.L.; Eberhart, M.S.; Dares, C.J.*; Meyer, T.J.* “Plasmon-Enhanced Light-Driven Water Oxidation by a Dye-Sensitized Photoanode” Proc. Natl. Acad. Sci. USA 2017, 114, 9809-9813.

22) Wang, D.; Sheridan, M.V.; Shan, B.; Farnum, B.H.; Marquard, S.L.; Sherman, B.D; Eberhart, M.S.; Nayak, A.; Dares, C.; Das, A.; Bullock, R.M.; Meyer, T.J.* “Layer-by-Layer Molecular Assemblies for Dye-Sensitized Photoelectrosynthesis Cells Prepared by Atomic Layer Deposition” J. Am. Chem. Soc. 2017, 139, 14518-14525.

21) Wang, D.; Farnum, B.H.; Sheridan, M.V.; Marquard, S.L.; Sherman, B.D.; Meyer, T.J.* “Inner Layer Control of Performance in a Dye-Sensitized Photoelectrosynthesis Cell” ACS Appl. Mater. Interfaces 2017, 9, 33533-33538.

20) Shan, B.; Farnum, B.H.; Wee, K-R.; Meyer, T.J.* “Generation of Long-Lived Redox Equivalents in Self-Assembled Bilayer Structure on Metal Oxide Electrodes” J. Phys. Chem. C 2017, 121, 5882-5890.

19) Coppo, R.L.; Farnum, B.H.; Sherman, B.D.; Neyde, Y.M.*; Meyer, T.J.* “The Role of Layer-by-Layer, Compact TiO₂ Films in Dye-Sensitized Photoelectrosynthesis Cells” Sustainable Energy & Fuels 2017, 1, 112-118.

18) Shan, B.; Das, A.K.; Marquard, S.; Farnum, B.H.; Wang, D.; Bullock, R.M.; Meyer, T.J.* “Photogeneration of Hydrogen from Water by a Robust Dye-Sensitized Photocathode” Energy Environ. Sci. 2016, 9, 3693-3697.

17) Farnum, B.H.; Wee, K-R.; Meyer, T.J.* “Self-Assembled Molecular p/n Junctions for Applications in Dye-Sensitized Photoelectrochemical Cells” Nature Chem. 2016, 8, 845-852.

16) Flynn, C.J.; McCullough, S.M.; Oh, E.E.; Li, L.; Mercado, C.C.; Farnum, B.H.; Li, W.; Donley, C.L.; You, W.; Nozik, A.J.; McBride, J.R.; Meyer, T.J.; Kanai, Y.; Cahoon, J. F.* “Site-Selective Passivation of Defects in NiO Solar Photocathodes by Targeted Atomic Deposition” ACS Appl. Mater. Interfaces 2016, 8, 4754-4761.

15) Farnum, B.H.; Nakada, A.; Ishitani, O.; Meyer, T.J.* “Bias-Dependent Oxidative and Reductive Quenching of a Molecular Excited-State Assembly Bound to a Transparent Conductive Oxide” J. Phys. Chem. C 2015, 119, 25180-25187.

14) Farnum, B.H.; Morseth, Z.A.; Brennaman, M.K.; Papanikolas, J.M.; Meyer, T.J.* “Application of Degenerately Doped Metal Oxides in the Study of Photoinduced Interfacial Electron Transfer” J. Phys. Chem. B 2015, 119, 7698-7711.

13) Garvey, T.; Farnum, B.H.; Lopez, R.* “Pulsed Laser Deposited Porous Nano-Carpets of Indium Tin Oxide Films and Their Use as Charge Collectors in Core-Shell Structures for Dye Sensitized Solar Cells” Nanoscale 2015, 7, 2400-2408.

12) Farnum, B.H.; Morseth, Z.A.; Brennaman, M.K.; Papanikolas, J.M.; Meyer, T.J.* “Drive Force Dependent Photo-induced Electron Transfer at Degenerately Doped, Optically Transparent Semiconductor Nanoparticle Interfaces” J. Am. Chem. Soc. 2014, 136, 15869-15872.

11) Wee, K-R.; Brennaman, M.K.; Alibabaei, L.; Farnum, B.H.; Sherman, B.; Lapides, A.M.; Meyer, T.J.* “Stabilization of Ruthenium(II) Polypyridyl Chromophores on Nanoparticle Metal Oxides Electrodes in Water by Hydrophobic PMMA Overlayers” J. Am. Chem. Soc. 2014, 136, 13514-13517.

10) Song, W.; Vannucci, A.K.; Farnum, B.H.; Lapides, A.M.; Brennaman, M.K.; Kalanyan, B.; Alibabaei, L.; Concepcion, J.J.; Losego, M.D.; Parsons, G.N.; Meyer, T.J.* “Visible Light Driven Benzyl Alcohol Dehydrogenation in a Dye-Sensitized Photoelectrosynthesis Cell” J. Am. Chem. Soc. 2014, 136, 9773-9779.

9) Alibabaei, L.; Farnum, B.H.; Kalanyan, B.; Brennaman, M.K.; Losego, M.; Parson, G.N.; Meyer, T.J.* “Atomic Layer Deposition of TiO₂ on Mesoporous nanoITO: Conductive Core-Shell Photoanodes for Dye-Sensitized Solar Cells” Nano Lett. 2014, 14, 3255-3261.

8) Farnum, B.H.; Morseth, Z.A.; Lapides, A.M.; Rieth, A.J.; Hoertz, P.G.; Brennaman, M.K.; Papanikolas, J.M.; Meyer, T.J.* “Photoinduced Interfacial Electron Transfer within a Mesoporous Transparent Conducting Oxide Film” J. Am. Chem. Soc. 2014, 136, 2208-2211.

7) Ward, W.M.; Farnum, B.H.; Siegler, M.; Meyer, G.J.* “Chloride Ion-Pairing with Ru(II) Polypyridyl Compounds in Dichloromethane” J. Phys. Chem. A 2013, 117, 8883-8894.

6) Farnum, B.H.; Ward, W.M.; Meyer, G.J.* “Flash-Quench Studies on the One-Electron Reduction of Triiodide” Inorg. Chem. 2013, 52, 840-847.

5) Farnum, B.H.; Jou, J.J.; Meyer, G.J.* “Visible Light Generation of I-I Bonds by Ru^II-tris(diimine) Excited-States” Proc. Natl. Acad. Sci. USA 2012, 109, 15628-15633.

4) Farnum, B.H.; Gardner, J.M.; Marton, A.; Narducci-Sarjeant, A.A.; Meyer, G.J.* “Influence of Ion Pairing on the Oxidation of Iodide by MLCT Excited States” Dalton Trans. 2011, 40, 3830-3838.

3) Rowley, J.G.; Farnum, B.H.; Ardo, S.; Meyer, G.J.* “Iodide Chemistry in Dye-Sensitized Solar Cells: Making and Breaking I-I Bonds for Solar Energy Conversion” J. Phys. Chem. Lett. 2010, 1, 3132-3140.

2) Farnum, B.H.; Gardner, J.M.; Meyer, G.J.* “Flash-Quench Technique Employed to Study the One-Electron Reduction of Triiodide in Acetonitrile: Evidence for a Diiodide Reaction Product” Inorg. Chem. 2010, 49, 10223-10225.

1) Gardner, J.M.; Abrahamsson, M.; Farnum, B.H.; Meyer, G.J.* “Visible Light Generation of Iodine Atoms and I-I Bonds: Sensitized I^– Oxidation and I₃^– Photodissociation” J. Am. Chem. Soc. 2009, 131, 16206-16214.